8/12/2011 4:08 AM
Daryck,
basis of pH H+ x OH- = 10^-14 it is about H+ and OH- not in H2O form
carbonates species : CO3--, HCO3-, carbonic acid
pH is about free ions precipitation ties up free ions
Fe, Mn, Cu, & Zn for instance get tied up with high pH because they precipitate into insoluble hydroxides
CEC is negative charge of soil colloids and organic matter as pH goes below 7 H and Al begin to adsorp to CEC
sulfates do not lower pH sulfur lowers pH because it forms H2SO4 interacting with soil water
cations are displaced in reverse order of their electrical attraction sodium goes first then K
sulfate of ammonia reduces pH because microbes release H+ from NH4
H+ doesn't adsorp to CEC until pH gets below 7
photosynthesis raises pH, this is why your irrigation lake could go from 7.8 at 6 am to 8.5 at 7pm, the microbes respire during night to bring pH back down
Carbonates do not drive pH, they are manipulated by it and act as buffer
metabolic processes drive pH and this is an area that needs further exploration
why can two waters with 250 mg/liter of bicarbonates have pH's of 6.5 and 8?
A chemical composition or reaction is favoring the precipitation of either more OH- in the lower pH water or more H+ in the higher pH water or a combination of the two